XCIII.—The reaction between methyl iodide and some metallic cyanides

Some Physiological Actions of Cyanides

1. The physiological actions of HCN and its salts appear to be due (a) to the ease with which HCN molecules penetrate living cells and then ionizing, exert their influence by means of H ions and CN ions; (b) to the weakness of HCN as an acid, which permits at neutrality or at even slight alkalinity the presence of a considerable amount of free HCN molecules in the presence of their salts; (c) t...

The chemistry of methyl iodide on Mo(100): formation and reaction of adsorbed methyl species

The adsorption of methyl iodide is studled on Mo (100) where ultraviolet photoelectron spectroscopy shows that the methyl lo&de thermally decomposes to form methyl species on warming to ~200 K This self-hydrogenates to yMd methane which desorbs at ~230 K and predosmg the surface with deuterium forms essentially only CH3D lndxcatmg that the methyl species reacts with adsorbed hydrogen and that t...

Methyl iodide poisoning.

Chlorine Dioxide-Iodide-Methyl Acetoacetate Oscillation Reaction Investigated by UV-Vis and Online FTIR Spectrophotometric Method

In order to study the chemical oscillatory behavior and mechanism of a new chlorine dioxide-iodide ion-methyl acetoacetate reaction system, a series of experiments were done by using UV-Vis and online FTIR spectrophotometric method. The initial concentrations of methyl acetoacetate, chlorine dioxide, potassium iodide, and sulfuric acid and the pH value have great influence on the oscillation ob...

(E)-1-Methyl-2-styrylpyridinium iodide

In the title compound, C(14)H(14)N(+)·I(-), the cation exists in an E configuration with respect to the ethenyl bond and is slightly twisted, the inter-planar angle between the pyridinium and phenyl rings of the cation being 4.8 (2)°. In the crystal packing, the cations are stacked in an anti-parallel fashion along the a axis by a π-π inter-action involving both pyridinium and phenyl rings; the...